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Evidence is mounting that graphene blisters in graphite electrodes play an important role in improving ion storage capacity. This review may arouse the emotions of researching graphene blisters in the field of energy storage nano-sized materials, especially for the electrode materials in DIBs.
In conclusion, the graphene blisters on the graphite surface exert a great impact on the battery performance. That is, the ability of the electrode to accommodate ions can be enhanced, and a stable electrode/electrolyte interface by forming the SEI in the inside can be obtained through forming the blisters.
The author used a tweezer to puncture the blister and the electrolyte flowed out, therefore, the phenomenon indicated that the electrolyte could reach the inner surfaces of blisters and both sides of the blisters could be used for charge storage.
Moreover, the volume change of the blisters with undamaged surfaces is reversible, and thus, it can play the role of increasing the specific capacity of the graphite cathode. Why do blisters exhibit such excellent elasticity without damaging the surface lattice?
The blistering on graphite can also enhance the electrochemical performances of other energy storage devices, for instance, the supercapacitors. Liu's group prepared partially exfoliated graphene through anion intercalation into multilayer graphene in phosphate buffer solution (pH = 6.68) containing 1 m KNO 3. [ 21]
Moreover, the activated graphene blisters possessed excellent elasticity, which was the basis for self-repairing of “defects” after standing. Notably, the graphene blisters could be well recovered to the original state after the first discharge.
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