
Up until the early 1990s, solar arrays used in space primarily used solar cells. Since the early 1990s, -based solar cells became favored over silicon because they have a higher efficiency and degrade more slowly than silicon in the space radiation environment. The most efficient solar cells currently in production are now . These use a combination of several layers of indium gallium phosphide, galli. [pdf]
Solar cell efficiency: According to NASA’s assessment (NASA, 2022), the state of the practice of solar cell efficiency in space today is 33%, while the state of the art is 70% (based on theoretical limits of 6-junction solar cells in laboratories today).
More specifically, III-V solar cells have become the standard technology for space power generation, mainly due to their high efficiency, reliability and ability to be integrated into very lightweight panels.
Crystalline silicon solar cell-based panels were used earlier to power satellites. At present, space solar arrays use III–V compound-based multijunction solar cells. Each solar cell has germanium, gallium indium arsenide, and gallium indium phosphide junction layers monolithically grown on a Ge wafer.
The International Space Station also uses solar arrays to power everything on the station. The 262,400 solar cells cover around 27,000 square feet (2,500 m 2) of space.
Si solar cells realized about 25% efficiency (research results on small area cells). The efficiency of the solar cell may be improved by combining two semiconductor p/n-junctions with different band gaps. For a one band gap cell the optimum efficiency is obtained for band gaps between 1.1 eV (Si) and 1.45 eV (GaAs).
Since the early 1990s, Gallium arsenide -based solar cells became favored over silicon because they have a higher efficiency and degrade more slowly than silicon in the space radiation environment. The most efficient solar cells currently in production are now multi-junction photovoltaic cells.

Third-generation photovoltaic cells are that are potentially able to overcome the of 31–41% power efficiency for single solar cells. This includes a range of alternatives to cells made of semiconducting ("first generation") and ("second generation"). Common third-generation systems include multi-layer ("tandem") cells made of or , while more theoretical developments include freq. [pdf]
Third-generation photovoltaic cells are solar cells that are potentially able to overcome the Shockley–Queisser limit of 31–41% power efficiency for single bandgap solar cells. This includes a range of alternatives to cells made of semiconducting p-n junctions ("first generation") and thin film cells ("second generation").
This review focuses on different types of third-generation solar cells such as dye-sensitized solar cells, Perovskite-based cells, organic photovoltaics, quantum dot solar cells, and tandem solar cells, a stacked form of different materials utilizing a maximum solar spectrum to achieve high power conversion efficiency.
Modified third-generation solar cells, for example, tandem and/or organic–inorganic configurations, are emerging as fourth-generation solar cells to maximize their economic efficiency. This chapter comprehensively covers the basic concepts, performance, and challenges associated with third-generation solar cells.
This review highlights not only different fabrication techniques used to improve efficiencies but also the challenges of commercializing these third-generation technologies. In theory, they are cheaper than silicon-based solar cells and can achieve efficiencies beyond the Shockley–Queisser limit.
Third-generation solar cell concepts have been proposed to address these two loss mechanisms in an attempt to improve solar cell performance. These solutions aim to exploit the entire spectrum by incorporating novel mechanisms to create new electron–hole pairs .
(3) Third generation, which are semiconducting-based solution-processed PV technologies [8, 9]. According to Green , third-generation solar cells are defined as those capable of high power-conversion efficiency while maintaining a low cost of production.

The allotropic forms of silicon range from a single crystalline structure to a completely unordered amorphous structure with several intermediate varieties. In addition, each of these different forms can possess several names and even more abbreviations, and often cause confusion to non-experts, especially as some materials and their application as a PV technology are of minor significa. In summary, single-crystalline silicon solar cells can be classified based on crystalline structure, technological advancements, and dopant type, each offering distinct characteristics and applicat. [pdf]
During the past few decades, crystalline silicon solar cells are mainly applied on the utilization of solar energy in large scale, which are mainly classified into three types, i.e., mono-crystalline silicon, multi-crystalline silicon and thin film, respectively .
The first generation of the solar cells, also called the crystalline silicon generation, reported by the International Renewable Energy Agency or IRENA has reached market maturity years ago . It consists of single-crystalline, also called mono, as well as multicrystalline, also called poly, silicon solar cells.
In solar cell fabrication, crystalline silicon is either referred to as the multicrystalline silicon (multi-Si) or monocrystalline silicon (mono-Si) [70–72]. The multi-Si is further categorized as the polycrystalline silicon (poly-Si) or the semi-crystalline silicon, consisting of small and multiple crystallites.
Crystalline silicon (c-Si), used in conventional wafer -based solar cells. Other materials, not classified as crystalline silicon, used in thin-film and other solar-cell technologies. Multi-junction solar cells (MJ) commonly used for solar panels on spacecraft for space-based solar power.
Silvija Gradečak, in Semiconductors and Semimetals, 2018 Crystalline silicon solar cells based on planar heterojunction architecture (Fig. 1 A) are currently the leading commercial photovoltaic (PV) technology, but there has been a significant effort to develop alternatives that overcome some of the limitations intrinsic to silicon photovoltaics.
Solar cells made from multi-crystalline silicon will have efficiencies up to ~22%, while 25% single junction monocrystalline silicon solar cells have been made from electronic grade silicon. Above 1414 °C, silicon is liquid. While crystalline silicon is semiconducting, liquid silicon is metallic and very reactive with air.
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